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- W2952809969 abstract "The first cobalt-catalyzed asymmetric Kumada cross-coupling with high enantioselectivity has been developed. The reaction affords a unique strategy for the enantioselective arylation of α-bromo esters catalyzed by a cobalt–bisoxazoline complex. A variety of chiral α-arylalkanoic esters were prepared in excellent enantioselectivity and yield (up to 97% ee and 96% yield). The arylated products were transformed into α-arylcarboxylic acids and primary alcohols without erosion of ee. The new enantioenriched α-arylpropionic esters synthesized herein are potentially useful in the development of nonsteroidal anti-inflammatory drugs. This method was conducted on gram-scale and applied to the synthesis of highly enantioenriched (S)-fenoprofen and (S)-ar-turmerone." @default.
- W2952809969 created "2019-06-27" @default.
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- W2952809969 date "2015-05-22" @default.
- W2952809969 modified "2023-09-27" @default.
- W2952809969 title "ChemInform Abstract: Cobalt-Bisoxazoline-Catalyzed Asymmetric Kumada Cross-Coupling of Racemic α-Bromo Esters with Aryl Grignard Reagents." @default.
- W2952809969 cites W2312964059 @default.
- W2952809969 doi "https://doi.org/10.1002/chin.201523083" @default.
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