Matches in SemOpenAlex for { <https://semopenalex.org/work/W2952837306> ?p ?o ?g. }
Showing items 1 to 90 of
90
with 100 items per page.
- W2952837306 endingPage "1240" @default.
- W2952837306 startingPage "1235" @default.
- W2952837306 abstract "Electron energy-loss spectroscopy (EELS) is used to determine the energies of low-lying singlet and triplet states of the title compound. The EELS measurements give a splitting of 0.45 eV between the two lowest π → π* singlet states, as confirmed by optical absorption measurements, but do not give a discernable splitting between the corresponding triplet states. The experimental results are interpreted with the aid of ab initio electronic structure calculations using the CIS and CASPT2 methods. The calculations are consistent with the experiments, giving a much larger splitting between the π → π* singlet as compared to the π → π* triplet states. They also reveal that the splitting between the two lowest π → π* triplet states is dominated by through-bond (TB) interactions, whereas that between the corresponding singlet states includes also a significant contribution from the dipole−dipole coupling mechanism." @default.
- W2952837306 created "2019-06-27" @default.
- W2952837306 creator A5015964741 @default.
- W2952837306 creator A5019158207 @default.
- W2952837306 creator A5031315673 @default.
- W2952837306 creator A5045764159 @default.
- W2952837306 creator A5087706538 @default.
- W2952837306 date "1996-01-01" @default.
- W2952837306 modified "2023-09-27" @default.
- W2952837306 title "Electronically Excited States of 1,4:5,8-Bismethano-1,4,4a,5,8,8a-hexahydronaphthalene, a Nonconjugated Diene: Comparison of Theory and Experiment" @default.
- W2952837306 cites W1968884052 @default.
- W2952837306 cites W1976451960 @default.
- W2952837306 cites W1985644977 @default.
- W2952837306 cites W1996725425 @default.
- W2952837306 cites W1997641598 @default.
- W2952837306 cites W2006947798 @default.
- W2952837306 cites W2031324175 @default.
- W2952837306 cites W2046412723 @default.
- W2952837306 cites W2075758407 @default.
- W2952837306 cites W2077513351 @default.
- W2952837306 cites W2079473982 @default.
- W2952837306 cites W2086309757 @default.
- W2952837306 cites W2164318957 @default.
- W2952837306 cites W2167373328 @default.
- W2952837306 cites W2950056355 @default.
- W2952837306 cites W2951992808 @default.
- W2952837306 cites W2951996084 @default.
- W2952837306 cites W3004527708 @default.
- W2952837306 cites W3004879352 @default.
- W2952837306 doi "https://doi.org/10.1021/ja9534664" @default.
- W2952837306 hasPublicationYear "1996" @default.
- W2952837306 type Work @default.
- W2952837306 sameAs 2952837306 @default.
- W2952837306 citedByCount "5" @default.
- W2952837306 countsByYear W29528373062020 @default.
- W2952837306 crossrefType "journal-article" @default.
- W2952837306 hasAuthorship W2952837306A5015964741 @default.
- W2952837306 hasAuthorship W2952837306A5019158207 @default.
- W2952837306 hasAuthorship W2952837306A5031315673 @default.
- W2952837306 hasAuthorship W2952837306A5045764159 @default.
- W2952837306 hasAuthorship W2952837306A5087706538 @default.
- W2952837306 hasConcept C121332964 @default.
- W2952837306 hasConcept C161522054 @default.
- W2952837306 hasConcept C173523689 @default.
- W2952837306 hasConcept C178790620 @default.
- W2952837306 hasConcept C181500209 @default.
- W2952837306 hasConcept C184779094 @default.
- W2952837306 hasConcept C185592680 @default.
- W2952837306 hasConcept C2777529809 @default.
- W2952837306 hasConcept C2781442258 @default.
- W2952837306 hasConcept C32891209 @default.
- W2952837306 hasConcept C33062035 @default.
- W2952837306 hasConcept C41999313 @default.
- W2952837306 hasConcept C62520636 @default.
- W2952837306 hasConcept C76766466 @default.
- W2952837306 hasConceptScore W2952837306C121332964 @default.
- W2952837306 hasConceptScore W2952837306C161522054 @default.
- W2952837306 hasConceptScore W2952837306C173523689 @default.
- W2952837306 hasConceptScore W2952837306C178790620 @default.
- W2952837306 hasConceptScore W2952837306C181500209 @default.
- W2952837306 hasConceptScore W2952837306C184779094 @default.
- W2952837306 hasConceptScore W2952837306C185592680 @default.
- W2952837306 hasConceptScore W2952837306C2777529809 @default.
- W2952837306 hasConceptScore W2952837306C2781442258 @default.
- W2952837306 hasConceptScore W2952837306C32891209 @default.
- W2952837306 hasConceptScore W2952837306C33062035 @default.
- W2952837306 hasConceptScore W2952837306C41999313 @default.
- W2952837306 hasConceptScore W2952837306C62520636 @default.
- W2952837306 hasConceptScore W2952837306C76766466 @default.
- W2952837306 hasIssue "6" @default.
- W2952837306 hasLocation W29528373061 @default.
- W2952837306 hasOpenAccess W2952837306 @default.
- W2952837306 hasPrimaryLocation W29528373061 @default.
- W2952837306 hasRelatedWork W1574257679 @default.
- W2952837306 hasRelatedWork W1964027433 @default.
- W2952837306 hasRelatedWork W1967887742 @default.
- W2952837306 hasRelatedWork W1990929531 @default.
- W2952837306 hasRelatedWork W2004793851 @default.
- W2952837306 hasRelatedWork W2058125928 @default.
- W2952837306 hasRelatedWork W2062673075 @default.
- W2952837306 hasRelatedWork W2068941732 @default.
- W2952837306 hasRelatedWork W2091883053 @default.
- W2952837306 hasRelatedWork W4245056051 @default.
- W2952837306 hasVolume "118" @default.
- W2952837306 isParatext "false" @default.
- W2952837306 isRetracted "false" @default.
- W2952837306 magId "2952837306" @default.
- W2952837306 workType "article" @default.