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- W2952840197 abstract "Cyclopropanation with diethyl bromomalonate and base (the Bingel reaction) was conducted on fullerene dimer C120 to give a mixture of “monoadducts” (45% yield) and “bisadducts” (≤37% yield), while 18% of the C120 remained unchanged. The “monoadducts” were separated into five positional isomers, i.e., eface, eedge, trans-4, trans-3, and trans-2, by preparative HPLC. Assignments were made based on 1H (and 13C) NMR and confirmed by theoretical calculations of the addends' 1H NMR chemical shifts. The relative yields of these isomers were in fair agreement with those observed for the Bingel bisaddition of C60. The Bingel reaction was also carried out on the dimer C120 encapsulating 3He in one of the C60 cages. Each positional isomer of the “monoadduct” exhibited a pair of 3He NMR signals corresponding to an isomer with functionalization on the 3He-containing cage and the other isomer with functionalization on the empty cage. Using the 3He NMR spectroscopy, a pair of signals for the trans-1 isomer, which eluded..." @default.
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- W2952840197 date "2010-05-22" @default.
- W2952840197 modified "2023-09-23" @default.
- W2952840197 title "ChemInform Abstract: Derivatization of Fullerene Dimer C120 by the Bingel Reaction and a 3He NMR Study of 3He@C120 Monoadducts." @default.
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- W2952840197 doi "https://doi.org/10.1002/chin.200208102" @default.
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