Matches in SemOpenAlex for { <https://semopenalex.org/work/W2952848488> ?p ?o ?g. }
Showing items 1 to 89 of
89
with 100 items per page.
- W2952848488 abstract "Abstract Microwave spectrum of fluorocyanoacetylene (FCCCN) produced by a glow discharge in pentafluorobenzonitrile (C 6 F 5 CN) was observed using a source-modulated spectrometer with a free-space absorption cell. Rotational transitions of FCCCN in the range of J = 9-8 to 20-19 were measured with an accuracy of 30 kHz for the ground state as well as for the vibrationally excited states, ν 5 ( ν 6 ( ν 7 (skeletal bend), 2 ν 6 , ν 5 + ν 7 , ν 6 + ν 7 , 2 ν 7 , 3 ν 7 , and 4 ν 7 . The rotational and centrifugal distortion constants obtained for the ground state are 2070.9571 ± 0.0006 MHz and 90.32 ± 0.95 Hz, respectively, where the uncertainties correspond to one standard deviation. The observed l -type doubling constants for the ν 5 (0.7718 ± 0.0002 MHz), ν 6 (0.9017 ± 0.0002 MHz), and ν 7 (2.0264 ± 0.0003 MHz) states agree with the values calculated from the harmonic force field. Anomalous behavior of the centrifugal distortion constants observed for some vibrational states was interpreted as due to the l -type resonance between sublevels with different l values. The unperturbed centrifugal distortion and l -type doubling constants and the intervals between sublevels were determined. Rotational transitions in the Σ + sublevel of the 2 ν 6 as well as the ν 5 + ν 7 state are perturbed by the Fermi resonance with the ν 4 (CC stretch) vibrational state." @default.
- W2952848488 created "2019-06-27" @default.
- W2952848488 creator A5025184192 @default.
- W2952848488 creator A5043957723 @default.
- W2952848488 creator A5075597870 @default.
- W2952848488 date "1989-04-11" @default.
- W2952848488 modified "2023-09-27" @default.
- W2952848488 title "ChemInform Abstract: Microwave Spectroscopy of FCCCN in the Ground and Excited Vibrational States." @default.
- W2952848488 cites W1970490444 @default.
- W2952848488 doi "https://doi.org/10.1002/chin.198915046" @default.
- W2952848488 hasPublicationYear "1989" @default.
- W2952848488 type Work @default.
- W2952848488 sameAs 2952848488 @default.
- W2952848488 citedByCount "0" @default.
- W2952848488 crossrefType "journal-article" @default.
- W2952848488 hasAuthorship W2952848488A5025184192 @default.
- W2952848488 hasAuthorship W2952848488A5043957723 @default.
- W2952848488 hasAuthorship W2952848488A5075597870 @default.
- W2952848488 hasConcept C113196181 @default.
- W2952848488 hasConcept C120665830 @default.
- W2952848488 hasConcept C121332964 @default.
- W2952848488 hasConcept C126780896 @default.
- W2952848488 hasConcept C139210041 @default.
- W2952848488 hasConcept C153642686 @default.
- W2952848488 hasConcept C178790620 @default.
- W2952848488 hasConcept C181500209 @default.
- W2952848488 hasConcept C184779094 @default.
- W2952848488 hasConcept C185592680 @default.
- W2952848488 hasConcept C194257627 @default.
- W2952848488 hasConcept C2776565987 @default.
- W2952848488 hasConcept C31100168 @default.
- W2952848488 hasConcept C32891209 @default.
- W2952848488 hasConcept C32909587 @default.
- W2952848488 hasConcept C33390570 @default.
- W2952848488 hasConcept C43617362 @default.
- W2952848488 hasConcept C44838205 @default.
- W2952848488 hasConcept C46362747 @default.
- W2952848488 hasConcept C49040817 @default.
- W2952848488 hasConcept C62520636 @default.
- W2952848488 hasConcept C69523127 @default.
- W2952848488 hasConceptScore W2952848488C113196181 @default.
- W2952848488 hasConceptScore W2952848488C120665830 @default.
- W2952848488 hasConceptScore W2952848488C121332964 @default.
- W2952848488 hasConceptScore W2952848488C126780896 @default.
- W2952848488 hasConceptScore W2952848488C139210041 @default.
- W2952848488 hasConceptScore W2952848488C153642686 @default.
- W2952848488 hasConceptScore W2952848488C178790620 @default.
- W2952848488 hasConceptScore W2952848488C181500209 @default.
- W2952848488 hasConceptScore W2952848488C184779094 @default.
- W2952848488 hasConceptScore W2952848488C185592680 @default.
- W2952848488 hasConceptScore W2952848488C194257627 @default.
- W2952848488 hasConceptScore W2952848488C2776565987 @default.
- W2952848488 hasConceptScore W2952848488C31100168 @default.
- W2952848488 hasConceptScore W2952848488C32891209 @default.
- W2952848488 hasConceptScore W2952848488C32909587 @default.
- W2952848488 hasConceptScore W2952848488C33390570 @default.
- W2952848488 hasConceptScore W2952848488C43617362 @default.
- W2952848488 hasConceptScore W2952848488C44838205 @default.
- W2952848488 hasConceptScore W2952848488C46362747 @default.
- W2952848488 hasConceptScore W2952848488C49040817 @default.
- W2952848488 hasConceptScore W2952848488C62520636 @default.
- W2952848488 hasConceptScore W2952848488C69523127 @default.
- W2952848488 hasLocation W29528484881 @default.
- W2952848488 hasOpenAccess W2952848488 @default.
- W2952848488 hasPrimaryLocation W29528484881 @default.
- W2952848488 hasRelatedWork W1970109493 @default.
- W2952848488 hasRelatedWork W1970475315 @default.
- W2952848488 hasRelatedWork W1970675045 @default.
- W2952848488 hasRelatedWork W1974559129 @default.
- W2952848488 hasRelatedWork W1978600654 @default.
- W2952848488 hasRelatedWork W1986380550 @default.
- W2952848488 hasRelatedWork W1997784462 @default.
- W2952848488 hasRelatedWork W1998695702 @default.
- W2952848488 hasRelatedWork W2001735185 @default.
- W2952848488 hasRelatedWork W2006758307 @default.
- W2952848488 hasRelatedWork W2008959626 @default.
- W2952848488 hasRelatedWork W2009980787 @default.
- W2952848488 hasRelatedWork W2013740227 @default.
- W2952848488 hasRelatedWork W2041994101 @default.
- W2952848488 hasRelatedWork W2064063767 @default.
- W2952848488 hasRelatedWork W2075869263 @default.
- W2952848488 hasRelatedWork W2949187102 @default.
- W2952848488 hasRelatedWork W2950022577 @default.
- W2952848488 hasRelatedWork W2991717929 @default.
- W2952848488 hasRelatedWork W3012759906 @default.
- W2952848488 isParatext "false" @default.
- W2952848488 isRetracted "false" @default.
- W2952848488 magId "2952848488" @default.
- W2952848488 workType "article" @default.