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- W2952854008 abstract "Diastereoselective Baylis-Hillman reaction of sugar-derived α,β-unsaturated δ-lactone with several aromatic aldehydes in presence of DABCO (50 mol%) to afford adducts in moderate to good yields (49-75%) with 30-82% de is being reported for the first time. Quantum chemical calculations based on the stabilities of transition structures and on the stabilities of zwitterionic intermediates rationalized the experimental observations." @default.
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- W2952854008 date "2006-01-01" @default.
- W2952854008 modified "2023-09-24" @default.
- W2952854008 title "Diastereoselective Baylis-Hillman Reaction: First Use of Sugar-Derived α,β-Unsaturated δ-Lactone as Chiral Michael Acceptor" @default.
- W2952854008 doi "https://doi.org/10.1055/s-2006-933099" @default.
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