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• W2952870811 startingPage "2772" @default.
• W2952870811 abstract "A rhodium-catalyzed asymmetric isomerization of racemic alpha-arylpropargyl alcohols to beta-chiral indanones has been developed. High enantioselectivity has been realized by the use of a newly developed axially chiral bisphosphine ligand. This ligand is unique in the sense that its axial chirality is fixed to a single configuration upon complexation to a transition metal due to other chiral axes existing within the same molecule." @default.
• W2952870811 created "2019-06-27" @default.
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• W2952870811 date "2006-02-09" @default.
• W2952870811 modified "2023-10-16" @default.
• W2952870811 title "Rhodium-Catalyzed Asymmetric Synthesis of Indanones: Development of a New “Axially Chiral” Bisphosphine Ligand" @default.
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• W2952870811 doi "https://doi.org/10.1021/ja056584s" @default.
• W2952870811 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16506735" @default.
• W2952870811 hasPublicationYear "2006" @default.
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