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- W2952875595 abstract "Abstract Transformation of the allylic amine of monosubstituted olefins into the aryl ketimine derivatives resulted in consistent higher anti diastereofacial selectivity in the osmium-catalyzed dihydroxylation reactions, compared to the selectivities obtained from commonly used allylic amino derivatives such as N -acyl, N -Boc or N , N -dibenzyl. The anti selectivity ranged from 3:1 to 7:1 in dry THF and the best was observed with the 3,3′-difluorobenzophenone ketimine derivative. Application of the ketimine group is also reported with the substrates of biological importance." @default.
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- W2952875595 date "2002-09-01" @default.
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- W2952875595 title "anti Selective dihydroxylation by the ketimine derivatives of the allylic amine in monosubstituted olefins" @default.
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- W2952875595 doi "https://doi.org/10.1016/s0040-4039(02)01654-4" @default.
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