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- W2952900639 abstract "α-Methyl β-amino diesters were synthesized in a simple three-step procedure starting from acylnitroso-derived Diels–Alder adducts of cyclopentadiene. Treatment of the cycloadducts with copper catalyst-modified methylmagnesium bromide gave anti-1,2-cyclopentenyl hydroxamic acids. Reduction of the hydroxamate NO bond with titanium(III) chloride followed by ozonolytic cleavage of the cyclopentenyl olefin provided the desired α-methyl β-amino diesters." @default.
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- W2952900639 date "2002-02-01" @default.
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- W2952900639 title "Novel α-substituted β-amino diesters from acylnitroso-derived hetero-Diels–Alder cycloadducts" @default.
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- W2952900639 doi "https://doi.org/10.1016/s0040-4039(01)02353-x" @default.
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