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- W2952904119 abstract "A series of unsymmetrical disulfides has been prepared by employing a reaction involving a ring opening, nucleophilic attack of a thiol on a 1,2-benzisothiazol-3-one. The benzisothiazolones were in turn prepared by an intramolecular ring closure of an amide on a sulfenyl thiocarbonate. The sulfenyl esters were synthesized as intermediates for preparing mixed-disulfides, but the benzisothiazolone ring closure occurred spontaneously. It was initially thought that the mixed-disulfides were being formed from the sulfenyl ester, but the isolation and stepwise reaction of the benzisothiazolones provided proof for the reaction mechanism." @default.
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- W2952904119 date "1997-09-01" @default.
- W2952904119 modified "2023-10-13" @default.
- W2952904119 title "A ring opening reaction of benzisothiazolones. A new route to unsymmetrical disulfides" @default.
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- W2952904119 doi "https://doi.org/10.1002/jhet.5570340515" @default.
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