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- W2952904394 abstract "Reaction of a range of transition-metal carbonyl anions [M]– with 2-chloro-1,3,2-dithiarsolane results in the formation of the metalloarsines [M–A[graphic omitted]]{M–=[Mo(CO)3(η-C5H5)]–, [W(CO)3(η-C5H5)]–, [Fe(CO)2(η-C5H5)]–, [Mn(CO)5]–, or [Re(CO)5]–}. There is no indication on an n.m.r. time-scale of pyramidal inversion about the arsenic atom in these complexes. Photolysis of [Mo(σ-A[graphic omitted])(CO)3(η-C5H5)] causes elimination of carbon monoxide and formation of [Mo(η2-A[graphic omitted])(CO)2(η-C5H5)] in which the dithiarsolane ring behaves as a dihapto, formally, three-electron donor. The reaction of 2-chloro-1,3,2-dithiarsolane with [Co(CO)4]– produces the dihapto product [Co(η2-[graphic omitted])(CO)3] directly." @default.
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- W2952904394 date "1989-09-05" @default.
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- W2952904394 title "ChemInform Abstract: Some Transition-Metal Complexes of 1,3,2-Dithiarsolane." @default.
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- W2952904394 doi "https://doi.org/10.1002/chin.198936279" @default.
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