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- W2952907281 abstract "This chapter examines the correlation of the solubility of low-volatile organic compounds in near-critical and supercritical fluids based on an accurate equation of state. A new noncubic equation of state has been presented and, first of all, successfully applied to correlate the pVT behavior of several supercritical solvents, such as the customary CO 2 as well as CC1F 3 or N 2 O. In the next step, this equation of state has been successfully applied on the modeling of solubility behaviour of low-volatile organic compounds in these solvents. These are four anthraquinone derivatives, P-carotene, and adamantine. Solubilities in a remarkably broad density range of the solvent have been modeled showing congruity between our theory and the experiments. The model predicts the occurrence of solubility maxima regardless of whether independently determined or along solubility isotherms fitted saturation pressures are considered or not. It is found that the saturation pressure of the particular solute, the low-volatile substance, can be deduced from the solubility isotherms." @default.
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- W2952907281 date "2004-01-01" @default.
- W2952907281 modified "2023-09-26" @default.
- W2952907281 title "Correlation of the solubility of low-volatile organic compounds in near- and supercritical fluids based on an accurate equation of state" @default.
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- W2952907281 doi "https://doi.org/10.1016/b978-044451574-2/50010-9" @default.
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