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- W2952912055 abstract "A general procedure for the syntheses of diarylmercurials is presented. Reactions proceeded in isopropanol in the presence of a base and arylboronic acid. With one exception, all reactions proceeded in good to excellent yields, and this procedure was applicable to a variety of aromatic and heteroaromatic boronic acids. Products were characterized by multinuclear NMR spectroscopy and microanalysis, and investigated by DFT calculations. The structure of di(4-pyridyl)mercury (6) was further authenticated by X-ray crystallography. Combined with previous work on the formation of arylgold(I) complexes via arylboronic acids, this procedure may be generally useful for the arylation of late transition metals." @default.
- W2952912055 created "2019-06-27" @default.
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- W2952912055 date "2009-01-01" @default.
- W2952912055 modified "2023-10-17" @default.
- W2952912055 title "Facile syntheses of homoleptic diarylmercurials via arylboronic acids" @default.
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- W2952912055 doi "https://doi.org/10.1016/j.jorganchem.2008.10.024" @default.
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