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- W2952912357 abstract "Triallyl(aryl)silanes, stable and easily accessible arylsilanes, were found to react with aryl bromides in the presence of a palladium catalyst (PdCl2–PCy3) and tetrabutylammonium fluoride (TBAF) in good yields. The scope of the reaction is broad, and a wide variety of functional groups are tolerant. Allyl groups on Si are readily cleaved upon treatment with TBAF to form fluorosilanes, silanepolyols, siloxanes and/or their mixed forms, which might be responsible for high efficiency of the reaction." @default.
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- W2952912357 date "2003-12-01" @default.
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- W2952912357 title "Triallyl(aryl)silanes serve as a convenient agent for silicon-based cross-coupling reaction of aryl halides" @default.
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- W2952912357 doi "https://doi.org/10.1016/j.jorganchem.2003.08.041" @default.
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