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- W2952920766 abstract "The crystal structures of the title compounds, [Sb(S2C·NEt2)3], (I), and [Bi(S2C·NEt2)3](II) have been determined from X-ray diffractometer data by the heavy-atom method and refined by least squares to R 0.07 (I), 3 [332 reflections] and 0.09 (II)[6 029 reflections]. Crystals of both are monoclinic, Z= 4, space group P21/a; (I): a= 14.665(5), b= 13.619(5), c= 12.642(4)A, β= 99.86(4)°; (II): a= 14.825(4), b= 13.640(2), c= 12.605(3)A, β= 100.01(3)°.(I) and (II) are isostructural; the symmetry of the M(S2C)3 unit resembles the C3 symmetry of the arsenic derivative, with three short M–S bonds fac, one from each ligand [M–S 2.487(4)–2.631(4)(I); 2.595(5)–2.775(5)A(II)], and three long bonds [M–S 2.886(4)–2.965(4)(I); 2.956(5)–2.964(4)A(II)], with a considerable gap in the co-ordination about the pseudo-C3 axis suggesting a stereochemically active lone-pair. The inversion image of the molecule approaches near this direction also, with a weak intermolecular metal–sulphur interaction [M ⋯ SI, 3.389(4)(I), 3.210(4)A(II)]." @default.
- W2952920766 created "2019-06-27" @default.
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- W2952920766 date "1976-07-13" @default.
- W2952920766 modified "2023-09-23" @default.
- W2952920766 title "ChemInform Abstract: CRYSTAL STRUCTURES OF TRIS(DIETHYLDITHIOCARBAMATO)-ANTIMONY(III) AND -BISMUTH(III)" @default.
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- W2952920766 doi "https://doi.org/10.1002/chin.197628063" @default.
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