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- W2952921581 abstract "A-nor B-aromatic steroidal skeleton was efficiently constructed by means of o-quinodimethane chemistry with exclusive stereoselectivity. The benzocyclobutene substrate for generation of the o-quinodimethane intermediate and subsequent [4+2] cycloaddition could be synthesized via (E)-selective Julia–Kocienski olefination and diastereoselective Grignard addition reactions. The synthesized tricyclic steroid-like compound with a trans-diol substructure would be utilized for divergent syntheses of potentially antitumor OSW-1 analogues with the truncated steroidal aglycone." @default.
- W2952921581 created "2019-06-27" @default.
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- W2952921581 date "2014-07-01" @default.
- W2952921581 modified "2023-10-09" @default.
- W2952921581 title "Stereoselective approach to potential scaffold of A-nor B-aromatic OSW-1 analogues via [4+2] cycloaddition of o-quinodimethane" @default.
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- W2952921581 doi "https://doi.org/10.1016/j.tet.2014.04.079" @default.
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