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- W2952926176 abstract "The molecular dipole moment and vector component of thehyperpolarisability of4-[N,N-bis(2-acetoxyethyl)amino]phenyl-1-azo-2′-(3′,5′-dinitrothiophene) have been calculated using asemi-empirical approach and the results compared with experimentalmeasurements in solution. The calculated values are found to be highlydependent on the conformation of the bis(2-acetoxyethyl)amino groupselected, though experimental results suggest that only certainconformations are preferred under the influence of an applied externalelectric field. The observed change in the sign of thehyperpolarisability in moving from an applied field to 0.925 to 1.17 eVis well reproduced by the calculations." @default.
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- W2952926176 date "2010-08-03" @default.
- W2952926176 modified "2023-09-26" @default.
- W2952926176 title "ChemInform Abstract: Non-Linear Optical Activity of Azo Dyes. Conformational Effects on the Quadratic Hyperpolarisability of an Azothiophene Dye." @default.
- W2952926176 cites W2004636630 @default.
- W2952926176 doi "https://doi.org/10.1002/chin.199740029" @default.
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