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- W2952940240 abstract "The enantioselective total synthesis of the antiinfective sesquiterpene (1S,4S)-7,8-dihydroxy-calamenene (4) is accomplished by a strategy which centrally utilizes the reactivity of arene-Cr(CO)3 complexes. In a sequence involving two successive benzylic deprotonation/alkylation steps, the chiral complex 8 (> 99% e.e.) is converted completely regio- and diastereoselectively to 7 and further by decomplexation and ether cleavage to the target compound 4 in high overall yield and without loss of enantiomeric purity." @default.
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- W2952940240 date "1993-09-01" @default.
- W2952940240 modified "2023-10-09" @default.
- W2952940240 title "Total synthesis of (1S,4S)-7,8-dihydroxycalamenene via benzylic alkylation of η6-arene-Cr(CO)3 complexes" @default.
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- W2952940240 doi "https://doi.org/10.1016/s0040-4039(00)73725-7" @default.
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