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- W2952948223 abstract "A catalytic asymmetric dearomatization of 2-naphthols with azodicarboxylates has been accomplished by using a N,N′-dioxide-scandium(III) complex as a chiral catalyst. A number of optically active β-naphthalenone compounds with a nitrogen-containing quaternary carbon stereocenter were obtained in up to 99 % yield and up to 99 % ee under mild reaction conditions. The reaction could be scaled up to a gram-scale with the yield and ee maintained. Based on these experiments and on previous reports, a possible transition state was proposed." @default.
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- W2952948223 date "2016-04-01" @default.
- W2952948223 modified "2023-09-23" @default.
- W2952948223 title "ChemInform Abstract: Chiral N,N′-Dioxide-Scandium(III)-Catalyzed Asymmetric Dearomatization of 2-Naphthols Through an Amination Reaction." @default.
- W2952948223 cites W1882007441 @default.
- W2952948223 doi "https://doi.org/10.1002/chin.201618098" @default.
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