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- W2952951451 abstract "In the presence of atmospheric oxygen, O-pentafluorobenzoyloximes having a (2,4-cyclohexadienyl)Fe(CO)3 moiety at the α-position cyclize smoothly to give trans-fused [(4,5,6,7-η)-3a,7a-dihydro-3H-indole]Fe(CO)3 complexes. The cyclization proceeds via radical chain mechanism initiated by molecular oxygen, in which pentafluorobenzoyloxyl radical plays a role as a chain carrier. Thus obtained trans-fused dihydroindole iron complexes readily isomerize to the cis-fused isomers on acidic silica gel or under basic conditions. Such isomers are converted to 3a,7a-dihydroindole or indole derivatives by the oxidative removal of the Fe(CO)3 group." @default.
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- W2952951451 date "2004-03-01" @default.
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- W2952951451 title "Radical Cyclization of<i>O</i>-Pentafluorobenzoyloximes Having a (Cyclohexadiene)Fe(CO)<sub>3</sub>Moiety" @default.
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- W2952951451 doi "https://doi.org/10.1246/bcsj.77.575" @default.
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