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- W2952954108 abstract "Data on the liquid-phase oxidation of isobutane at 50 and 100°C have been reexamined, using a modified mechanism to take into account the termination by isobutylperoxy radicals. Algebraic expressions are derived from steady-state methods. Using Arrhenius parameters fitted by transition-state A factors and activation energies derived from observed “best” rate constants, new sets of parameters are derived for the rate constants for propagation by tBuO2 + tBuH t-BuO2H + tBu⋅: where θ = 2.303RT in kcal/mol. This, together with new values for the termination parameters and rates of i-butyl production by k4B, is shown to give good agreement with the published data. An important reaction:is shown to quench the possible contributions to termination of adventitious radicals such as CH3O⋅2." @default.
- W2952954108 created "2019-06-27" @default.
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- W2952954108 date "1980-08-26" @default.
- W2952954108 modified "2023-09-28" @default.
- W2952954108 title "ChemInform Abstract: LIQUID-PHASE OXIDATION OF ISOBUTANE - A REANALYSIS OF THE DATA" @default.
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- W2952954108 doi "https://doi.org/10.1002/chin.198034128" @default.
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