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- W2952956279 abstract "A gold(I)-catalyzed synthesis of indanones from trimethylsilylacetylenes and acylsilanes is presented. The reaction is initiated through a synergistic acylsilane activation-gold acetylide formation and involves consecutive alkyne σ-gold(I) addition, π-activation, and 1,2-migration of a silyl group. Studies performed on the reaction mechanism allowed to establish the nature of the silyl migrating group and invoke the participation of a gold(I) carbenoid intermediate. The reaction is completed by a gold(I) C-H functionalization step." @default.
- W2952956279 created "2019-06-27" @default.
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- W2952956279 date "2016-02-01" @default.
- W2952956279 modified "2023-09-27" @default.
- W2952956279 title "ChemInform Abstract: Gold(I)-Catalyzed Addition of Silylacetylenes to Acylsilanes: Synthesis of Indanones by C-H Functionalization Through a Gold(I) Carbenoid." @default.
- W2952956279 cites W2097574390 @default.
- W2952956279 doi "https://doi.org/10.1002/chin.201611115" @default.
- W2952956279 hasPublicationYear "2016" @default.
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