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- W2952959175 abstract "Abstract The asymmetric conjugate reduction of 3-aryl-4-phosphonobutenoates has been demonstrated which provides an enantioselective synthesis of optically active 3-aryl-4-phosphonobutyric acid esters. A wide range of 3-aryl-4-phosphonobutenoate derivates are reduced with high enantioselectivities (up to 94% ee) using an ( S )-Segphos/Cu(OAc) 2 ·H 2 O catalyst system (1 or 5 mol %) in the presence of PMHS and t -BuOH. The reduction is influenced by the steric and electronic effects of the substrates." @default.
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- W2952959175 date "2012-05-31" @default.
- W2952959175 modified "2023-09-28" @default.
- W2952959175 title "ChemInform Abstract: An Enantioselective Synthesis of 3-Aryl-4-phosphonobutyric Acid Esters via Cu-Catalyzed Asymmetric Conjugate Reduction." @default.
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- W2952959175 doi "https://doi.org/10.1002/chin.201226198" @default.
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