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- W2952960715 abstract "A new general concept for the total synthesis of pseurotin A (1), a secondary metabolite of Pseudeurotium ovalis STOLK, which possesses a highly substituted 1-oxa-7-azaspiro[4.4]nonane skeleton, is presented. A key intermediate of the planned reaction sequence is the functionalized γ-lactone 8. The corresponding protected compound 52 was prepared using (S)-O,O-isopropylideneglyceraldehyde (13) and the bromoacetal 14 as starting material. γ-Lactone 52 was obtained in enantiomerically pure state in ten steps. It possesses the desired configuration." @default.
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- W2952960715 date "1995-08-09" @default.
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- W2952960715 title "Synthetic Studies towards Pseurotin A. Part 3. Synthesis of a related highly functionalized ?-lactone" @default.
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- W2952960715 doi "https://doi.org/10.1002/hlca.19950780518" @default.
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