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- W2952976474 abstract "A strategy for dual transition metal catalysis and organocatalysis is reported via the in situ disintegration of a single rhodium complex. The hereby generated chiral Lewis acid and L-β-phenylalanine synergistically catalyze the Michael addition of α,α-disubstituted aldehydes to α,β-unsaturated 2-acyl imidazoles under the formation of vicinal quaternary/tertiary stereocenters. Conveniently, the chiral-at-metal rhodium catalyst can be synthesized in just two steps starting from rhodium trichloride without the need for any chromatography." @default.
- W2952976474 created "2019-06-27" @default.
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- W2952976474 date "2016-09-01" @default.
- W2952976474 modified "2023-09-27" @default.
- W2952976474 title "ChemInform Abstract: Asymmetric Dual Catalysis via Fragmentation of a Single Rhodium Precursor Complex." @default.
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- W2952976474 doi "https://doi.org/10.1002/chin.201642136" @default.
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