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- W2952988706 abstract "Optically pure β,β-dimethylated amino acid building blocks with functionalized side chains have been prepared from d-aspartic acid. The dimethylation was accomplished by regioselective dialkylation of 9-phenylfluorenyl (PhFl)-protected aspartate diesters. The bulk of the PhFl protecting group also allowed for a variety of functional group manipulations to be carried out on the side chain without affecting the Cα ester of the aspartate. As a result, the derivatives of the following novel amino acids were synthesized in this study: β,β-dimethyl-d-aspartic acid, β,β-dimethyl-d-homoserine, 3,3-dimethyl-d-2,4-diaminobutyric acid, β,β-dimethyl-d-lysine, β,β-dimethyl-d-homoglutamate, β,β-dimethyl-d-ornithine, and 3,3-dimethylazetidine-2-carboxylic acid. The β,β-dimethylated amino acids were synthesized in high enantiomeric excess as determined by coupling the novel building blocks to chiral reagents." @default.
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- W2952988706 date "1999-05-25" @default.
- W2952988706 modified "2023-09-24" @default.
- W2952988706 title "Synthesis of β,β-Dimethylated Amino Acid Building Blocks Utilizing the 9-Phenylfluorenyl Protecting Group" @default.
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- W2952988706 doi "https://doi.org/10.1021/jo982474a" @default.
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