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- W2952997255 abstract "Cyclocondensation of acetone in volves aldol condensati on leading initiall y to the primary condensation products (PCP), di acetone alcohol and mesityl ox ide, which again react with acetone to form phorone, isophorone, mesitylene. etc. Relative selectivities of chromia, y-alumina, magnesia and calci um oxide catalys ts have been stud ied in a flow reactor at 360-520 'c. Alu mi na and magnesia are found to favo ur isophorone fo rmation at 360 'c with 45% selectivi ty but the selectivity steeply fa ll s with the increase in temperatu re to 520 'c due to rise in decomposition products.' Primary condensation products are formed more wi th magnesia; selecti vity to mesitylene is mo re wi th CaO (-66% at 40U-480 'C) and Cr20 ] (50-55% at 480-520 ' C)." @default.
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- W2952997255 date "1999-01-01" @default.
- W2952997255 modified "2023-09-24" @default.
- W2952997255 title "CATALYTIC CYCLOCONDENSATION OF ACETONE TO ISOPHORONE" @default.
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