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- W2953018136 abstract "The reaction of a primary zinc amide with a diorganozinc reagent gives a secondary amine in the presence of Fe(acac)3 as a catalyst and 1,2-dichloroisobutane (DCIB) as an oxidant. Halogen groups such as F, Cl, Br, and I are tolerated well. The dichloride oxidant and heat are essential to achieve the C–N bond formation presumably from a catalytic iron intermediate species bearing aryl and amido groups." @default.
- W2953018136 created "2019-06-27" @default.
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- W2953018136 date "2011-10-18" @default.
- W2953018136 modified "2023-10-03" @default.
- W2953018136 title "Iron-Catalyzed Oxidative Monoarylation of Primary Amines with Organozinc Reagents" @default.
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- W2953018136 doi "https://doi.org/10.1021/ol2024357" @default.
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