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- W2953019737 abstract "Abstract β -Fluorosulphatoperfluoroalkyl radicals ( 3, 7 and 8 ) are obtained by the reaction of fluoroolefins (HFP trimer and dimer, and perfluoro4 4-dimethylpent-2-ene, respectively) with (FSO 3 ) 2 . The pure β -fluorosulphatotetrafluoroethylperfluorodiisopropylmethyl radical ( 3 ) has been isolated and converted to the perfluoroacetyldiisopropylmethyl radical ( 4 ) under the action of CsF. The reaction of radicals 3,7 and 8 with SbF 5 leads to the replacement of the FSO 3 group by a fluorine atom. The ability of the FSO 3 group in β -fluorosulphatoperfluoroalkyl radicals to play the role of a leaving group is explained by the stabilizing effect of the unshared electron on the adjacent carbocation centre." @default.
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- W2953019737 date "2010-08-04" @default.
- W2953019737 modified "2023-09-26" @default.
- W2953019737 title "ChemInform Abstract: Stable Fluoroaliphatic Radicals Containing Functional Groups: Synthesis and Reactivity." @default.
- W2953019737 cites W1998706714 @default.
- W2953019737 doi "https://doi.org/10.1002/chin.199716073" @default.
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