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- W2953022451 abstract "Abstract The new R 2 TAl 4 Ge 2 (R = Y, Gd–Er, T = Fe, Co) quaternary compounds have been synthesized and studied by powder XRD, SEM and MPMS techniques. It is found that the R 2 TAl 4 Ge 2 compounds crystallized in the tetragonal Tb 2 NiAl 4 Ge 2 -type structure with space group I 4 /mmm (No. 139). The crystal structures of Gd 2 CoAl 4 Ge 2 and Gd 2 FeAl 4 Ge 2 were successfully refined by using Rietveld method. The magnetic measurements of Gd 2 CoAl 4 Ge 2 and Gd 2 FeAl 4 Ge 2 show antiferromagnetic ordering at lower temperature. The susceptibilities of Gd 2 CoAl 4 Ge 2 and Gd 2 FeAl 4 Ge 2 are followed perfectly by Curie–Weiss behavior in high temperature region. The magnetic measurement shows that the effective magnetic moment is μ eff = 8.10 μ B (per Gd atom) and the paramagnetic Curie temperature is θ p = −31.1 K for Gd 2 CoAl 4 Ge 2 , while the effective magnetic moment of Gd 2 FeAl 4 Ge 2 is μ eff = 8.27 μ B (per Gd atom) and the paramagnetic Curie temperature is θ p = −13.7 K. The isothermal magnetization of Gd 2 TAl 4 Ge 2 (T = Fe, Co) were also investigated." @default.
- W2953022451 created "2019-06-27" @default.
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- W2953022451 date "2015-05-22" @default.
- W2953022451 modified "2023-09-23" @default.
- W2953022451 title "ChemInform Abstract: Crystal Structure of New R2TAl4Ge2(R: Y, Gd-Er, T: Fe, Co) Quaternary Compounds and Magnetic Properties of Gd2TAl4Ge2." @default.
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- W2953022451 doi "https://doi.org/10.1002/chin.201523003" @default.
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