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- W2953042610 abstract "Synthesis of benzyl α- and β-kasugaminides (benzyl 2,4-diamino-2,3,4,6-tetradeoxy-α- and β-D-arabino-hexopyranosides) was carried out by the simultaneous substitution at 2,4-positions of 2,4-di-O-mesyl-abequosides (3,6-dideoxy-2,4-di-O-mesyl-α- and β-D-xylo-hexopyranosides) with sodium azide followed by hydrogenation. The substitution in N,N-dimethylformamide at higher temperature gave the elimination products (4-azido-2,3-unsaturated derivatives) and the subsequently rearranged products (3,4-unsaturated 2-azido derivatives), but, that in hexamethylphosphoric triamide at lower temperature gave the desired compounds in fairly good yields." @default.
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- W2953042610 date "1978-02-21" @default.
- W2953042610 modified "2023-09-27" @default.
- W2953042610 title "ChemInform Abstract: AMINOSUGARS. XXVIII. A FACILE SYNTHESIS OF BENZYL α- AND β-KASUGAMINIDES VIA THE CORRESPONDING ABEQUOSIDES" @default.
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- W2953042610 doi "https://doi.org/10.1002/chin.197808316" @default.
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