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- W2953043359 abstract "An oxidative cascade cyclization of β-keto esters has been developed for the construction of the tricyclic picrotoxane motif in a single step, and DFT calculations suggested a possible cationic cyclization mechanism. This cascade cyclization can be operated on a 20 g scale to obtain a 77% total yield of the tricyclic products, which in turn can be converted to versatile intermediates for further elaboration to picrotoxanes and their structurally related compounds." @default.
- W2953043359 created "2019-06-27" @default.
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- W2953043359 date "2019-06-12" @default.
- W2953043359 modified "2023-10-15" @default.
- W2953043359 title "Synthesis of the Tricyclic Picrotoxane Motif by an Oxidative Cascade Cyclization" @default.
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- W2953043359 doi "https://doi.org/10.1021/acs.orglett.9b01806" @default.
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