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- W2953061764 abstract "Scope of the copper catalyzed/mediated selenium-nitrogen coupling reaction has been studied for the synthesis of isoselenazolones. It is noticed that the 2-chloro, 2-bromo-, and 2-iodo-aryl amides substrates can be exploited in the selenium–nitrogen coupling reaction by employing 25–100 mol % of CuI/1,10-phenanthroline (L) and potassium carbonate as a base in DMF. Furthermore, electron rich 2-chloro-arylamides also underwent selenium–nitrogen coupling reaction to give biologically important selenium–nitrogen heterocycles. Also, copper-catalyzed selenium–nitrogen coupling reaction has been meticulously applied for the synthesis of diaryl diselenides having methoxy, amine, and amide functionality from respective aryl iodides in the presence of stoichiometric amount of succinimide as an external Se–N coupling partner." @default.
- W2953061764 created "2019-06-27" @default.
- W2953061764 creator A5012998766 @default.
- W2953061764 creator A5037474329 @default.
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- W2953061764 date "2011-12-01" @default.
- W2953061764 modified "2023-10-07" @default.
- W2953061764 title "Copper catalyzed/mediated synthetic methodology for ebselen and related isoselenazolones" @default.
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- W2953061764 doi "https://doi.org/10.1016/j.tet.2011.09.141" @default.
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