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- W2953080287 abstract "Cyclization of (5-N-pyrrolyl-2-hydroxypentyl)cobaloxime (13) proceeds by intramolecular electrophilic aromatic substitution of a cobaloxime π-cation onto the pyrrole ring to provide 6-exo cyclization product (14) in 95% yield. This cyclization is highly enantioselective. It is applied to a synthesis of highly enantioenriched (−)-tashiromine, (−)-21, and a formal synthesis of (+)-tashiromine." @default.
- W2953080287 created "2019-06-27" @default.
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- W2953080287 date "1997-10-01" @default.
- W2953080287 modified "2023-09-28" @default.
- W2953080287 title "A synthesis of (−)-tashiromine and formal synthesis of (+)-tashiromine utilizing a highly enantioselective pyrrole/cobaloxime π-cation cyclization" @default.
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- W2953080287 doi "https://doi.org/10.1016/s0040-4039(97)01638-9" @default.
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