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- W2953083135 abstract "Structurally diverse macrocycles and medium-sized rings (9-24 membered scaffolds, 22 examples) can be generated through a telescoped acylation/ring-expansion sequence, leading to the insertion of linear fragments into cyclic β-ketoesters without performing a discrete macrocyclization step. The key β-ketoester motif is regenerated in the ring-expanded product, meaning that the same sequence of steps can then be repeated (in theory indefinitely) with other linear fragments, allowing macrocycles with precise substitution patterns to be grown from smaller rings using the successive ring-expansion (SuRE) method." @default.
- W2953083135 created "2019-06-27" @default.
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- W2953083135 date "2016-04-01" @default.
- W2953083135 modified "2023-09-27" @default.
- W2953083135 title "ChemInform Abstract: The Synthesis of Structurally Diverse Macrocycles by Successive Ring Expansion." @default.
- W2953083135 cites W2166233859 @default.
- W2953083135 doi "https://doi.org/10.1002/chin.201617188" @default.
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