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- W2953103484 abstract "Diastereoisomers of the 1,3-dienes RCMeCMeCMeCMeR (2, RCO2CH3; 7, RCH2OCH3) have been prepared. The configurations at the CC bonds (Schemes 2 and 3) and the conformations of these chiral dienes were investigated by several spectroscopic methods. The barriers to partial rotation about the central CC single bond in (E,E)-, (E,Z)-, and (Z,Z)-2 were determined by dynamic 1H NMR in the presence of the optically active lanthanide complex (+)-Eu(hfbc)3. The ΔG≠-values (Table 6) allow conclusions to be drawn about the structure of the s-trans transition state of rotation." @default.
- W2953103484 created "2019-06-27" @default.
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- W2953103484 date "1983-04-05" @default.
- W2953103484 modified "2023-09-24" @default.
- W2953103484 title "ChemInform Abstract: CHIRAL BUTADIENES. 10. BARRIERS TO ENANTIOMERIZATION OF 1,2,3,4-TETRAMETHYL-1,3-BUTADIENES" @default.
- W2953103484 cites W1976096238 @default.
- W2953103484 doi "https://doi.org/10.1002/chin.198314075" @default.
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