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- W2953131543 abstract "Emission properties of Eu2+-doped Ba(Sr, Ca)2MgSi2O8 are discussed in terms of the crystal structure refined by Rietveld method. Ba(Sr, Ca)2MgSi2O8 has glaserite-type layered structure. In response to Sr/(Sr+Ca) ratio, the layer-framework build up by corner-sharing of MgO6 octahedra and SiO4 tetrahedra twists around C3 axes to match the size of B-site cation (Sr2+/Ca2+). This twist significantly affects the unit cell size and the coordination environment around B-site. Eu2+-doped Ba(Sr, Ca)2MgSi2O8 exhibited blue emission under ultraviolet irradiation. The emission spectra have been characterized by two emission components derived from Eu2+ ions occupying A- and B-site. Both components showed similar wavelength shift for different Sr/(Sr+Ca), in response to Si–O1 polarization and to the structural change." @default.
- W2953131543 created "2019-06-27" @default.
- W2953131543 creator A5023977124 @default.
- W2953131543 date "2013-05-01" @default.
- W2953131543 modified "2023-09-24" @default.
- W2953131543 title "Structural consideration on the emission properties of Eu2+-doped Ba(Sr, Ca)2MgSi2O8" @default.
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- W2953131543 doi "https://doi.org/10.1016/j.jssc.2013.01.036" @default.
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