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- W2953134482 abstract "Cyclic voltammetry and preparative-scale electrochemical studies on the intramolecular cyclization of allyl 2-halophenyl ethers catalyzed by Ni(II)−cyclam complexes leads us to propose a mechanism involving Ni(I) and Ni(III) intermediate species. The role of Mg2+ ions in the reactivity and selectivity of the process is discussed. The Ni(cyclam)Br2-catalyzed electrosynthesis of dihydrobenzofurans and dihydrobenzopyrans from unsaturated side-chain aryl halide derivatives is effected in good yields in the presence of a magnesium anode." @default.
- W2953134482 created "2019-06-27" @default.
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- W2953134482 date "1998-07-25" @default.
- W2953134482 modified "2023-09-25" @default.
- W2953134482 title "Electrochemical Studies of Ni(cyclam)<sup>2+</sup>-Catalyzed Annulation Reactions" @default.
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- W2953134482 doi "https://doi.org/10.1021/om980247t" @default.
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