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• W2953147742 abstract "Abstract An efficient procedure for the preparation of trans-2,6-diaryl piperidinones has been developed. Addition of aryl Grignard reagents to 2-aryl dihydropyridones under catalytic copper promoted conditions generates the trans isomer exclusively, an unprecedented stereochemical event. The X-ray structures of both starting material and product have been solved and shed light on the steric constraints and substrate geometry leading to the observed product. The reaction conditions tolerate a variety of aromatic nucleophiles to generate C2-symmetric products in good overall yields." @default.
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• W2953147742 date "2007-03-01" @default.
• W2953147742 modified "2023-09-24" @default.
• W2953147742 title "Synthesis of C2-symmetric trans-2,6-diarylpiperidinones via aryl cuprate addition: an unexpected stereochemical outcome" @default.
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• W2953147742 doi "https://doi.org/10.1016/j.tetlet.2007.01.135" @default.
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