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- W2953152332 abstract "Natural Medicine Research Center, KRIBB, Daejeon 305-806, KoreaReceived August 19, 2008Poly-substituted pyrrole derivatives were synthesized from Baylis-Hillman adducts via the following consecu-tive reactions comprised of (i) bromination of the Baylis-Hillman adduct, (ii) In-mediated Barbier reaction withaldehyde, (iii) PCC oxidation to α-methylene-γ-keto ester, (iv) reaction with amine to form enamine inter-mediate, (v) Michael type cyclization, and the final (vi) aerobic oxidation. Key Words : Pyrroles, Baylis-Hillman adducts, Barbier reaction, PCC, Aerobic oxidation IntroductionSuitably substituted pyrroles are the basic skeleton ofmany biologically important substances" @default.
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- W2953152332 date "2008-11-20" @default.
- W2953152332 modified "2023-10-12" @default.
- W2953152332 title "Regioselective Synthesis of Poly-Substituted Pyrroles from Baylis-Hillman Adducts via the [3+1+N] Annulation Strategy" @default.
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- W2953152332 doi "https://doi.org/10.5012/bkcs.2008.29.11.2215" @default.
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