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- W2953160858 abstract "A source configuration that lies intermediate to a low-pressure effusing molecular beam and a high-pressure flow device is used to generate boron cluster molecules in a highly oxidizing environment. Using this source operating in an NO/sub 2/ oxidative environment, the authors generate a chemiluminescent emission spectrum, which they attribute to the asymmetric BBO molecule. The observed spectrum is characterized by a strong ..delta nu.. = ..delta nu.. = 40 cm/sup /minus/1/ sequence grouping and a weaker ..delta nu.. = + 1 sequence (..delta nu.. = 40 cm/sup /minus/1/), 440 cm/sup /minus/1/ to higher energy. A second sequence with ..delta nu.. /approximately/ 142 cm/sup /minus/1/ is also observed. Combining the 440-cm/sup /minus/1/ upper-state frequency with the 142-cm/sup /minus/1/ sequence structure implies a lower-state frequency of /approximately/ 582 cm/sup /minus/1/ for the B-B stretch, consistent with ab initio calculation." @default.
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- W2953160858 date "1989-03-07" @default.
- W2953160858 modified "2023-09-27" @default.
- W2953160858 title "ChemInform Abstract: Oxidation of Small Boron Agglomerates: Formation of and Chemiluminescent Emission from BBO." @default.
- W2953160858 cites W137469970 @default.
- W2953160858 doi "https://doi.org/10.1002/chin.198910028" @default.
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