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- W2953167334 abstract "The kinetics of the following silylene eliminations in the gas phase have been measured: Me3SiSiMe2Cl → Me2Si + Me3SiCl, log10k/s–1=(11.69 ± 0.33)–(209.7 ± 4.5) kJ mol–1/2.303 RT, Cl2MeSiSiMe2Cl → MeSiCl + Me2SiCl2, log10k/s–1=(12.45 ± 0.76)–(195.6 ± 10.0) kJ mol–1/2.303 RT, Cl2MeSiSiMeCl2→ MeSiCl + MeSiCl3, log10k/s–1=(12.06 ± 0.35)–(192.4 ± 4.6) kJ mol–1/2.303 RT. The significance of these Arrhenius parameters is discussed. Some insertion reactions of dimethylsilylene and methylsilylene are described." @default.
- W2953167334 created "2019-06-27" @default.
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- W2953167334 date "1976-10-05" @default.
- W2953167334 modified "2023-09-27" @default.
- W2953167334 title "ChemInform Abstract: FORMATION OF SILYLENES IN THE THERMOLYSIS OF METHYLCHLORODISILANES" @default.
- W2953167334 cites W1985733629 @default.
- W2953167334 doi "https://doi.org/10.1002/chin.197640095" @default.
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