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- W2953171000 abstract "The synthesis of trichlorotris(tetrahydrofuran)molybdenum(III) is described. This complex reacts with tertiary phosphines (PR3, R = alkyl or aryl) to yield [MoCl3(PR3)3], [MoCl3(thf)(PR3)2], or [MoCl3(thf)2(PR3)](thf = tetrahydrofuran) depending on the size of R. Some binuclear complexes have also been isolated. The complex [MoCl3(thf)3] reacts with various phosphines and magnesium or sodium amalgam in the presence of nitrogen to form molybdenum(0) complexes including [Mo(N2)2(PMe2Ph)4], [Mo(N2)2(Ph2PCH2CH2PPh2)2], [Mo(PH2Ph)6], and [Mo(Ph2PCH2PPh2)3]." @default.
- W2953171000 created "2019-06-27" @default.
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- W2953171000 date "1976-03-09" @default.
- W2953171000 modified "2023-09-26" @default.
- W2953171000 title "ChemInform Abstract: PREPARATION OF TRICHLOROTRIS(TETRAHYDROFURAN)MOLYBDENUM(III) AND ITS USE IN THE PREPARATION OF COMPLEXES OF MOLYBDENUM(III) AND -(0)" @default.
- W2953171000 cites W2105857458 @default.
- W2953171000 doi "https://doi.org/10.1002/chin.197610293" @default.
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