Matches in SemOpenAlex for { <https://semopenalex.org/work/W2953174540> ?p ?o ?g. }
Showing items 1 to 92 of
92
with 100 items per page.
- W2953174540 endingPage "13756" @default.
- W2953174540 startingPage "13752" @default.
- W2953174540 abstract "The arene ligand in the complex TpRe(CO)(MeIm)(η2-benzene) (Tp = hydridotris(pyrazolyl)borate; MeIm = N-methylimidazole) undergoes tandem electrophile/nucleophile 1,4-addition reactions. Subsequent oxidative demetalation affords cis-3,6-disubstituted 1,4-cyclohexadienes (46−84%). Common organic electrophiles such as acetals and Michael acceptors were successfully added to the bound benzene to generate η3-benzenium complexes, which then were treated with a silyl ketene acetal, silyl vinyl ether, phenyllithium, or malonate ester to afford 1,4-dialkylated dihydrobenzene complexes. The d6 transition metal analogues TpW(NO)(PMe3)(η2-benzene) and [Os(NH3)5(η2-benzene)]2+ also undergo 1,4-dialkylation reactions, and the relative ability of all three metals to activate arenes is compared." @default.
- W2953174540 created "2019-06-27" @default.
- W2953174540 creator A5004243536 @default.
- W2953174540 creator A5086797540 @default.
- W2953174540 date "2004-10-01" @default.
- W2953174540 modified "2023-09-26" @default.
- W2953174540 title "Stereoselective Tandem 1,4-Addition Reactions for Benzenes: A Comparison of Os(II), Re(I), and W(0) Systems" @default.
- W2953174540 cites W1983222953 @default.
- W2953174540 cites W1993737343 @default.
- W2953174540 cites W2014001561 @default.
- W2953174540 cites W2018725294 @default.
- W2953174540 cites W2036710301 @default.
- W2953174540 cites W2040117622 @default.
- W2953174540 cites W2072063277 @default.
- W2953174540 cites W2088087324 @default.
- W2953174540 cites W2151635324 @default.
- W2953174540 cites W2171948791 @default.
- W2953174540 doi "https://doi.org/10.1021/ja047108p" @default.
- W2953174540 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15493934" @default.
- W2953174540 hasPublicationYear "2004" @default.
- W2953174540 type Work @default.
- W2953174540 sameAs 2953174540 @default.
- W2953174540 citedByCount "15" @default.
- W2953174540 countsByYear W29531745402012 @default.
- W2953174540 countsByYear W29531745402015 @default.
- W2953174540 countsByYear W29531745402017 @default.
- W2953174540 countsByYear W29531745402019 @default.
- W2953174540 countsByYear W29531745402020 @default.
- W2953174540 countsByYear W29531745402021 @default.
- W2953174540 crossrefType "journal-article" @default.
- W2953174540 hasAuthorship W2953174540A5004243536 @default.
- W2953174540 hasAuthorship W2953174540A5086797540 @default.
- W2953174540 hasConcept C116569031 @default.
- W2953174540 hasConcept C155647269 @default.
- W2953174540 hasConcept C161790260 @default.
- W2953174540 hasConcept C170493617 @default.
- W2953174540 hasConcept C178790620 @default.
- W2953174540 hasConcept C178907741 @default.
- W2953174540 hasConcept C181647583 @default.
- W2953174540 hasConcept C185592680 @default.
- W2953174540 hasConcept C2777270887 @default.
- W2953174540 hasConcept C2777552763 @default.
- W2953174540 hasConcept C2777691172 @default.
- W2953174540 hasConcept C2777731525 @default.
- W2953174540 hasConcept C2778874822 @default.
- W2953174540 hasConcept C50027330 @default.
- W2953174540 hasConcept C5304478 @default.
- W2953174540 hasConcept C55493867 @default.
- W2953174540 hasConcept C58548122 @default.
- W2953174540 hasConcept C71240020 @default.
- W2953174540 hasConcept C94882840 @default.
- W2953174540 hasConceptScore W2953174540C116569031 @default.
- W2953174540 hasConceptScore W2953174540C155647269 @default.
- W2953174540 hasConceptScore W2953174540C161790260 @default.
- W2953174540 hasConceptScore W2953174540C170493617 @default.
- W2953174540 hasConceptScore W2953174540C178790620 @default.
- W2953174540 hasConceptScore W2953174540C178907741 @default.
- W2953174540 hasConceptScore W2953174540C181647583 @default.
- W2953174540 hasConceptScore W2953174540C185592680 @default.
- W2953174540 hasConceptScore W2953174540C2777270887 @default.
- W2953174540 hasConceptScore W2953174540C2777552763 @default.
- W2953174540 hasConceptScore W2953174540C2777691172 @default.
- W2953174540 hasConceptScore W2953174540C2777731525 @default.
- W2953174540 hasConceptScore W2953174540C2778874822 @default.
- W2953174540 hasConceptScore W2953174540C50027330 @default.
- W2953174540 hasConceptScore W2953174540C5304478 @default.
- W2953174540 hasConceptScore W2953174540C55493867 @default.
- W2953174540 hasConceptScore W2953174540C58548122 @default.
- W2953174540 hasConceptScore W2953174540C71240020 @default.
- W2953174540 hasConceptScore W2953174540C94882840 @default.
- W2953174540 hasIssue "42" @default.
- W2953174540 hasLocation W29531745401 @default.
- W2953174540 hasLocation W29531745402 @default.
- W2953174540 hasOpenAccess W2953174540 @default.
- W2953174540 hasPrimaryLocation W29531745401 @default.
- W2953174540 hasRelatedWork W1975996446 @default.
- W2953174540 hasRelatedWork W2041639000 @default.
- W2953174540 hasRelatedWork W2088415474 @default.
- W2953174540 hasRelatedWork W2094942239 @default.
- W2953174540 hasRelatedWork W2098235972 @default.
- W2953174540 hasRelatedWork W2949519439 @default.
- W2953174540 hasRelatedWork W2950249869 @default.
- W2953174540 hasRelatedWork W2951408533 @default.
- W2953174540 hasRelatedWork W2953174540 @default.
- W2953174540 hasRelatedWork W3215000159 @default.
- W2953174540 hasVolume "126" @default.
- W2953174540 isParatext "false" @default.
- W2953174540 isRetracted "false" @default.
- W2953174540 magId "2953174540" @default.
- W2953174540 workType "article" @default.