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- W2953186945 abstract "Highly substituted unnatural α-amino esters, for example, ethyl 3-alkyl-4-(aryl or vinyl)-2-(N-4-methoxyphenylamine)pent-4-enoates were prepared in a regiocontrolled and diastereoselective manner via Pd(II)-catalyzed three-component coupling of boronic acids and allenes with ethyl iminoacetate relying on the umpolung of the traditional electrophilicity of mono-π-allylpalladium complexes. The 2-aminopent-4-enoates were subjected to N-allylation and intramolecular ring-closing metathesis to afford tetrahydropyridines featuring an α-amino ester group." @default.
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- W2953186945 date "2007-11-01" @default.
- W2953186945 modified "2023-09-26" @default.
- W2953186945 title "Synthesis of Unnatural <b>α</b>-Amino Acid Derivatives via a Three-Component Coupling Method Utilizing an Allylpalladium Umpolung" @default.
- W2953186945 doi "https://doi.org/10.1055/s-2007-990845" @default.
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