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- W2953193073 abstract "The rhodium(I)-catalyzed cycloisomerization of enynes with tethered (S)-2-methyl-2-propanesulfinyl imine affords 5- or 6-membered cyclic compounds containing exocyclic 1,3-diene moieties in a stereoselective manner. The reaction proceeds through β-hydride elimination of a 7-membered azarhodacycle intermediate, which is generated from three unsaturated bonds (i.e., alkene, alkyne, and CN bonds) and an Rh(I) complex. The resultant cyclic compounds could be reacted with various dienophiles to afford spiroamides as single isomers through the Diels–Alder reaction." @default.
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- W2953193073 date "2016-11-01" @default.
- W2953193073 modified "2023-09-27" @default.
- W2953193073 title "ChemInform Abstract: Rhodium(I)-Catalyzed Diastereoselective Cycloisomerization of Enynes with Tethered (S)-2-Methyl-2-propanesulfinyl Imine." @default.
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- W2953193073 doi "https://doi.org/10.1002/chin.201650025" @default.
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