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• W2953193817 abstract "In the presence of a palladium catalyst and NaOAc, aryl iodides react with 1-aryl-1-alkynes to afford 9-alkylidene-9H-fluorenes in good yields. The products from this reaction are highly dependent on the base employed. This process appears to involve (1) oxidative addition of the aryl iodide to Pd(0), (2) alkyne insertion, (3) rearrangement of the resulting vinylic palladium intermediate to an arylpalladium species, and (4) aryl-aryl coupling with simultaneous regeneration of the Pd(0) catalyst. Consistent with this mechanism is the fact that 9-alkylidene-9H-fluorenes can also be prepared by the Pd-catalyzed rearrangement of 1,1-diaryl-2-iodo-1-alkenes." @default.
• W2953193817 created "2019-06-27" @default.
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• W2953193817 creator A5061187623 @default.
• W2953193817 date "2001-10-06" @default.
• W2953193817 modified "2023-10-16" @default.
• W2953193817 title "Synthesis of 9-Alkylidene-9<i>H</i>-fluorenes by a Novel, Palladium-Catalyzed Cascade Reaction of Aryl Halides and 1-Aryl-1-alkynes" @default.
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• W2953193817 doi "https://doi.org/10.1021/jo010561o" @default.
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