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- W2953196118 abstract "Cyclopropanation was performed using the Furukawa procedure with CH2I2/Et2Zn and α,β-unsaturated ketones. The reaction was performed in the presence of a copper salt. The reactivity was highly dependent on the substrate structure, and cyclopropanated products were obtained in better yields than those achieved using the original Simmons–Smith conditions with a Zn–Cu couple in some cases. Stereospecificity was observed in a certain case; however, the synthesis of an asymmetric version with a chiral ligand was not successful." @default.
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- W2953196118 date "2014-05-05" @default.
- W2953196118 modified "2023-09-30" @default.
- W2953196118 title "Another Role of Copper in the Simmons–Smith Reaction: Copper-catalyzed Nucleophilic Michael-type Cyclopropanation of α,β-Unsaturated Ketones" @default.
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- W2953196118 doi "https://doi.org/10.1246/cl.131193" @default.
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