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- W2953202365 abstract "The nature of catalytic asymmetric dihydroxylation (AD), in particular the problem of ligand leaching from insoluble polymer-bound (IPB) Cinchona alkaloid derivatives, has been investigated. An upper limit to the amount of dissolved ligand, and methods for its evaluation, which assure a basically heterogeneous character of the observed AD reaction, are presented. A new copolymer architecture, which meets the established stability requirements and allows the highly enantioselective (87-99 % ee) IPB-AD of representative alkene substrates, is also described." @default.
- W2953202365 created "2019-06-27" @default.
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- W2953202365 date "2005-08-02" @default.
- W2953202365 modified "2023-09-24" @default.
- W2953202365 title "Asymmetric Dihydroxylation with Recoverable Cinchona Alkaloid Derivatives: A Warning Note and an Improved, Insoluble Polymer-Bound Ligand Architecture." @default.
- W2953202365 cites W2099809928 @default.
- W2953202365 doi "https://doi.org/10.1002/chin.200531048" @default.
- W2953202365 hasPublicationYear "2005" @default.
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