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- W2953202811 abstract "Substituent effects may tune and alter the optical and electronic properties of ligands and the complexes which they comprise. We review the effect of electron-withdrawing and -donating groups on the dipyridophenazine (dppz) framework. The observation of selected modulation of the properties associated with the phenazine or phenanthroline MOs is observed and reflected in the electrochemical and optical properties. The effect of donor groups that can give rise to ligand-centred charge-transfer optical transitions is also discussed. The effect of substituents on complexes with triazole ligands is examined; in stark contrast to the findings for dppz systems, and virtually regardless of the type of triazole ligand, substituents have only a muted effect on optical and electrochemical properties." @default.
- W2953202811 created "2019-06-27" @default.
- W2953202811 creator A5003961363 @default.
- W2953202811 creator A5034549401 @default.
- W2953202811 creator A5075147918 @default.
- W2953202811 date "2015-01-01" @default.
- W2953202811 modified "2023-10-11" @default.
- W2953202811 title "Substituent effects on the electronic properties of complexes with dipyridophenazine and triazole ligands: Electronically connected and disconnected ligands" @default.
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- W2953202811 doi "https://doi.org/10.1016/j.ccr.2014.05.003" @default.
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