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- W2953203742 abstract "Abstract The reaction of 5′-C-thymidine aldehyde with allytrimethylsilane promoted by BF3:Et2O lead stereoselectively to 5′-C(S)-allylthymidine which is converted to 5′-C(S)-hydroxyhexylthymidine. 5′-C-(R or S) hydroxypentylthymidine can be obtained by using ω-tertButyldimethylsilyloxyallyltrimethylsilane in the Sakurai reaction. In the same conditions, ω-Bromoallyltrimethylsilane adds to the aldehyde with a complete transposition of the siliranium intermediate and allows the preparation of the 5′-C(S)-bromopentene derivative." @default.
- W2953203742 created "2019-06-27" @default.
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- W2953203742 date "2010-06-14" @default.
- W2953203742 modified "2023-10-01" @default.
- W2953203742 title "ChemInform Abstract: Allylsilanes in the Preparation of 5′-C-Hydroxy or Bromo Alkylthymidines." @default.
- W2953203742 cites W2116091450 @default.
- W2953203742 doi "https://doi.org/10.1002/chin.199933247" @default.
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